1258327-08-0
- Product Name:(11aS)-12-Hydroxy-1,10-di(naphthalen-1-yl)-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide
- Molecular Formula:C37H27O4P
- Purity:99%
- Molecular Weight:566.593
Product Details
pd_meltingpoint:>300℃
Purity:99%
Sale Buy Reliable Quality (11aS)-12-Hydroxy-1,10-di(naphthalen-1-yl)-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide 1258327-08-0 Efficient Shipping
- Molecular Formula:C37H27O4P
- Molecular Weight:566.593
- Melting Point:>300℃
- PSA:65.57000
- Density:1.44
- LogP:9.37710
1258327-08-0 Relevant articles
SPINOL-derived phosphoric acids: Synthesis and application in enantioselective Friedel-Crafts reaction of indoles with imines
Xu, Fangxi,Huang, Dan,Han, Chao,Shen, Wei,Lin, Xufeng,Wang, Yanguang
, p. 8677 - 8680 (2010)
A new class of chiral phosphoric acids w...
1258327-08-0 Process route
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1292849-40-1
(S)-6,6'-di(naphthalen-1-yl)-1,1'-spirobiindane-7,7'-diol
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1258327-08-0,1297613-73-0
(S)-6,6-di(naphthalen-1-yl)-1,1'-spirobiindane-7,7'-diyl phosphate
Conditions | Yield |
---|---|
(S)-6,6'-di(naphthalen-1-yl)-1,1'-spirobiindane-7,7'-diol;
With
pyridine; trichlorophosphate;
at 0 - 70 ℃;
for 3h;
Inert atmosphere;
With
water;
at 0 - 110 ℃;
for 4h;
Inert atmosphere;
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(S)-7,7'-bis(1-methoxymethoxy)-1,1'-spirobiindane
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1258327-08-0,1297613-73-0
(S)-6,6-di(naphthalen-1-yl)-1,1'-spirobiindane-7,7'-diyl phosphate
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps
1.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / diethyl ether; hexane / 6 h / -78 - 20 °C / Inert atmosphere
1.2: -78 - 20 °C / Inert atmosphere
2.1: hydrogenchloride / methanol; chloroform; water / 3 h / Inert atmosphere; Reflux
3.1: 5% Pd(II)/C(eggshell); potassium carbonate / 1,4-dioxane; water / 2 h / 80 °C / Inert atmosphere
4.1: pyridine; trichlorophosphate / 3 h / 0 - 70 °C / Inert atmosphere
4.2: 4 h / 0 - 110 °C / Inert atmosphere
With
pyridine; hydrogenchloride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; 5% Pd(II)/C(eggshell); potassium carbonate; trichlorophosphate;
In
1,4-dioxane; methanol; diethyl ether; hexane; chloroform; water;
3.1: Suzuki coupling;
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1258327-08-0 Upstream products
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(S)-6,6'-di(naphthalen-1-yl)-1,1'-spirobiindane-7,7'-diol
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1-Naphthylboronic acid